The 40-year-old social media savant threw her arms up into the air and smized at the camera while posing in front of a metallic background.
Kim's flawless makeup was highlighted by sky-high cheekbones and bold brows as she posed for the campaign.
Earlier in the morning, she shared that working out is 'just good for the soul' while she took a few steps on her treadmill.
Kim commanded attention this week in two dazzling metallic outfits designed to accentuate her hourglass figure as she promoted her latest fragrance.
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Featuring a cleavage-enhancing bodice and matching trousers, Kim's first - a striking silver two-piece - dominates as she reclines on a distinctive love heart shaped seat, a reference to the scent's distinctive bottle.
With her hair pulled into a tight ponytail, the reality star offers a piercing stare in the first of nine images posted on behalf of her latest venture.
Kim also models a stunning gold version of the same outfit, with its tight corset drawing further attention to her slimline waist.
Captioning the new set, she wrote: 'Three new luxurious aromas encased in metallic heart-shaped bottles, plus the restock of three of our original KKW Hearts fragrances BAE, BFF & WIFEY.
'Just in time for Valentine’s Day, gift for yourself and/or a loved one!'
It's understood that Kim will reportedly discuss the end of her marriage to Kanye during the final series of the family's E! reality show Keeping Up With The Kardashians, much to the horror of the Bound 2 rapper, a source told Usweekly.
'He is less than thrilled,' a source said as he continues to stay in Wyoming on his ranch while Kim remains with all four of their children at their Hidden Hills, California mansion.
The source added: 'She will continue to focus on her business empire. Kim has been in individual counselling and is at peace with where her life is headed.'
